Synthesis of ricinoleate anion based ionic liquids and their application as green lubricating oil additives

Abstract

Ricinoleate anion based ionic liquids (ILs) were synthesized from four different nitrogen containing cationic counterparts such as tetrabutylammonium, tetrapropylammonium, cetyltrimethylammonium, imidazolium. Tribological performance of synthesized ILs were evaluated using four ball tribo tester by blending with two lubricant base oils namely epoxy2-ethylhexyl esters of karanja fatty acids (EKE) and dioctyl sebacate (DOS). Antiwear behaviour was explored by varying different factors including concentration, applied load and rotation speed. It was found that the synthesized ILs in base oil significantly reduced the wear scar diameter by 17–25% at 0.8 wt% and a remarkable reduction in wear scar diameter was observed for all the tested applied load (40 to 80 kg) and rotation speed (1200 to 1742 rpm). Further, the load carrying capacity of base oil was improved by 25–43% at 1.25 wt% of IL dosage. The imidazolium cation containing IL outperform tribological performance among all the ILs being studied. The morphology of worn surface after the wear tests and deposition of elementals on the worn surface lubricated with neat base oil and IL blended base oil was studied by scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDX).