Abstract
Polysiloxane derivative (MPS), obtained from the reaction of polymeric tributylstannyl ester of silicic acid (PTBS) and (3-methacryloyloxypropyl)dimethylchlorosilane (1a), was shown to be a useful inorganic component for the preparation of organic-inorganic hybrid resin as a nanocomposite. Copolymerization of MPS containing methacryloyloxypropyl groups with the common monomer such as styrene, acrylonitrile, or methyl methacrylate proceeded readily at room temperature under UV irradiation to give the corresponding resins (HR). The resins obtained from MPS and methyl methacrylate showed a good transparency and resistance in scratch test, but a poor flexibility. The gels consisted of analogous structure to HR were obtained from PTBS, 1a, and the monomer by one-pot procedure, in which substitution and polymerization proceeded simultaneously.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call