Abstract
We synthesize poly(oligoaniline)s consisting of multiple oligoaniline units linked by alkane spacers with their structures and properties controlled over three different oxidation states. tert-Butoxycarbonyl (t-BOC)-protected diamino-oligoanilines are synthesized and polymerized with diisocyanatoalkanes to produce t-BOC-protected prepolymers. We obtain the unprotected poly(oligoaniline)s in leucoemeraldine base, emeraldine base, and emeraldine salt oxidation forms by using different deprotection conditions for each of them. Distinct routes to each oxidation form of poly(oligoaniline)s enable exploitation of the crystalline structure, electrochemical activity, or conductivity, which is expected from the oligoaniline-based materials, as well as their excellent processability into thin films that arises from their polymeric nature. The results suggest that new functional materials based on poly(oligoaniline)s may be derived by developing efficient synthetic procedures to control the oxidation states, promising for creation of new nanostructured materials with electrochemical activities. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Polymer Science Part A: Polymer Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
