Abstract
Nanosized palladium cluster-catalyzed Suzuki–Miyaura coupling polymerization of 1,1′-binaphthyldiyl-bearing diiodides with expanded π-conjugated aromatic diboronic acid pinacol diesters affords aromatic polyketones, which have blue-emitting fluorescent properties (λ em 450–489 nm) in addition to high thermal stability (T g 190–297 °C) and excellent solubility in common organic solvents such as DMSO and NMP.
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