Abstract

Abstract Palladium nanocluster-catalyzed Suzuki–Miyaura coupling polymerization of 2,2′-bis(iodobenzoylphenoxy)-1,1′-binaphthyls 2 with aromatic diboric acid diesters 3 proceeded smoothly, affording 1,1′-binaphthyl-2,2′-dioxy-bearing aromatic polyketones 4. The resulting polyketones 4 have excellent thermal stability and solubility in typical organic solvents.

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