Abstract
Controllable synthesis of zinc sulfide (ZnS) nanocrystals (NCs)/polymer transparent nanocomposite hybrids in situ based on the catalytic chain transfer polymerization (CCTP) technique. Firstly, a polymeric ligand PMAA (PMAA = poly(acrylic acid)) with controllable low-molecular-weight and a terminal double bond was synthesized through CCTP Catalytic chain transfer polymerization (CCTP) has emerged as an efficacious method to produce low- molecular weight polymers. In this paper, we reported the first controllable synthesis of nanosilica surface-grafted poly(methyl methacrylate) (PMMA) (SI-PMMA) macromonomers by using bis(aqua)bis((difluoroboryl)- dimethylglyoximato)cobalt(II) (CoBF) as a chain transfer catalyst via CCTP.
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