Abstract
Abstract A series of mono-and dinuclear ruthenium(II) complexes of the type [CP(EPh3)RuL]-/+, [(bipy)2RuL]0/2+, [Ru2Cp2(EPh3)4L], [Ru2CP2(EPh3)3L]2+, [Ru2Cp(EPh3)2(bipy)2]+/3+ [E = P0. As, Sb; L = S2C2(CN)2 2-or (C6H5CH2)2S2C2(CN)2] have been synthesised exploiting the nucleophilicity of S and N in L. The complexes have been characterized by microanalyses, conductance, IR, 1H and 31 P NMR and UV-visible spectral data.
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