Synthesis of luminescent nanocrystals and solid solutions in the YNbO4–EuNbO4 system via hydrothermal route

Abstract

Luminescent nanocrystals having distinctive ellipsoidal morphology and the complete solid solution of monoclinic phase in the YNbO4–EuNbO4 system were hydrothermally formed under weakly basic conditions at 180–240°C for 5h. The excitation spectra of the Y1−xEuxNbO4 nanocrystals, which consisted of the charge transfer (CT) band around 240–270nm due to [NbO4]3−–Eu3+ interaction and several sharp bands corresponding to the f–f transitions of Eu3+, e.g. the most intense absorption band at 395nm (7F0→5L6), showed that the compounds could be excited by both ultraviolet and visible light. A dominant red emission at 610nm and a weak orange emission at 590nm assigned to 5D0→7F2 and 5D0→7F1 transitions of Eu3+, respectively were observed in the as-prepared nanocrystals containing europium under excitation at 395nm. The heat treatment at temperatures more than 1000°C in air was effective for the improvement in the photoluminescence intensity of the as-prepared solid solutions. By the enhancement in the crystallinity and crystallite growth of the monoclinic phase through heat treatment at 1300°C in air, the luminescence intensity of the as-prepared solid solution, Y0.75Eu0.25NbO4 (x=0.25), which showed the most significant photoluminescence, became more than 5 times as strong as that before the heat treatment.