Synthesis of LiNi0.5Mn1.5O4 by solid-state reaction with improved electrochemical performance

Abstract

LiNi0.5Mn1.5O4 spinel samples were synthesized by a two-step solid-state reaction method. Manganese acetate and nickel acetate were mixed together in a molar ratio of 3:1 and reacted at 500°C to form a mixed Ni-Mn oxide, which reacted subsequently with lithium acetate at 900°C to form a LiNi0.5Mn1.5O4 powder. For comparison, manganese acetate, nickel acetate and lithium acetate were mixed together in a molar ratio of 3:1:2 and directly reacted in one-step at 900°C. The LiNi0.5Mn1.5O4 powder synthesized from the two-step process shows enhanced conductivity and improved rate performance. X-ray diffraction and Raman spectroscopy analyses indicate that the two-step sample has a space group of Fd3¯m while the one-step sample has a space group of P4332. The cyclic voltammetry test has confirmed that lithium-ion cells with the two-step sample in the positive electrode exhibit lower impedance than those with the one-step sample.