Electrochemical properties of nano- and micro-sized LiNi 0.5Mn 1.5O 4 synthesized via thermal decomposition of a ternary eutectic Li–Ni–Mn acetate

Abstract

Nano- and micro-sized LiNi 0.5Mn 1.5O 4 particles are prepared via the thermal decomposition of a ternary eutectic Li–Ni–Mn acetate. Lithium acetate, nickel acetate and manganese acetate can form a ternary eutectic Li–Ni–Mn acetate below 80 °C. After further calcination, nano-sized LiNi 0.5Mn 1.5O 4 particles can be obtained at an extremely low temperature (500 °C). When the sintering temperature goes above 700 °C, the particle size increases, and at 900 °C micro-sized LiNi 0.5Mn 1.5O 4 particles (with a diameter of about 4 μm) are obtained. Electrochemical tests show that the micro-sized LiNi 0.5Mn 1.5O 4 powders (sintered at 900 °C) exhibit the best capacity retention at 25 °C, and after 100 cycles, 97% of initial discharge capacity can still be reached. Nano-sized LiNi 0.5Mn 1.5O 4 powders (sintered at 700 °C) perform the best at low temperatures; when cycled at −10 °C and charged and discharged at a rate of 1 C, nano-sized LiNi 0.5Mn 1.5O 4 powders can deliver a capacity as high as 110 mAh g −1.