Synthesis of hybrid framework of tenorite and octahedrally coordinated aluminosilicate for the robust adsorption of cationic and anionic dyes

Abstract

Adsorption is an important process for the industrial dye effluent treatment. Many adsorbents are employed such as activated carbon, metal oxide, molecular sieves etc. All those adsorbents are having their own setbacks like longer adsorption time and lower adsorption capacity. So development of fast adsorption and higher adsorption capacity is very much essential. In this view, we synthesized hybrid crystal system of tenorite and aluminosilicate framework (CuO@AS) for the faster adsorption. It is characterized by FT-IR, HRTEM and WAXRD. WAXRD proved the hybridization of two crystal systems viz tenorite & alumina in monoclinic phase and silica in trigonal phase. The crystal structure drawn based on the WAXRD data. It is observed that the tenorite and aluminosilicate framework are separate, but they are interlinked through Cu–O–Al and Cu–O–Si bond. This interconnection makes the aluminium in six coordination and Cu in four coordination. Aluminium and copper has 3 and 2 Brønsted acid sites respectively. Moreover, copper has three more OH group, so totally 5 H+ and 3 OH− sites in copper and aluminium are responsible for the faster adsorption with high adsorption capacity compared to reported literature. To test the adsorption tendency, Victoria Blue (VB) and Metanil Yellow (MY) dyes are employed at room temperature. The rate constant of Pseudo-second order kinetics for the VB and MY are 0.002462 g mg−1 min−1 and 0.001619 g mg−1 min−1 which indicated faster adsorption of VB than MY. Moreover, total adsorption capacity for VB (636 mg/g) is higher than MY (52 mg/g). This is due to the hybridization of tenorite and aluminosilicate. Thermodynamic data such as ΔG°, ΔH° and ΔS° revealed that the adsorption is spontaneous, chemisorption and highly disordered in the adsorbent-adsorbate interface. This disorderness is due to the disordered pores present in the material.