Room temperature fabrication of cobalt mullite for the snappy adsorption of cationic and anionic dyes

Abstract

Cobalt mullite adsorbent for the robust adsorption performance toward Victoria Blue (VB) and Metanil Yellow (MY) is fabricated by the sol-gel method at room temperature using dipropylamine as a structure-directing agent. The synthesized adsorbent is characterized by XRD, FT-IR, and HRTEM. From these analyses, it is found that dipropylamine binds with the alumina and cobalt oxide, which makes it into tetrahedral to octahedral form. This interaction causes the formation of cobalt mullite. It is observed that trigonal alumina and orthorhombic cobalt mullite are interlinked to form a hybrid network. The special feature of adopting this adsorbent for the adsorption of VB and MY is that it has a large amount of Brønsted acid site because of the octahedral coordination of Al and Co. The large availability of acid sites in the framework and hybridization of two different network systems favors robust adsorption. The rate of adsorption (K2 = 0.00402g/mg.min for VB and K2 = 0.004g/mg.min for MY) and adsorption capacity (Qe = 102.041mg/g for VB and Qe = 19.0406mg/g for MY) are greater for VB than MY. This may be due to the more steric factor involved in MY than VB. Thermodynamic parameter indicated that the adsorption of VB and MY is spontaneous, endothermic, and increased randomness in the adsorbent-adsorbate interface. The results from the enthalpy value (ΔH° = 65.43kJ/mol for VB and ΔH° = 44.729kJ/mol for MY) revealed that the chemisorption is involved in the adsorption process.