Synthesis of Fe3O4/CdS-ZnS nanostructure and its application for photocatalytic degradation of chlorpyrifos pesticide and brilliant green dye from aqueous solutions.

Abstract

Chlorpyrifos (CP) is an organophosphorus pesticide used to control pests in agriculture. Brilliant green (BG) is a cationic dye widely used in textile and dyeing industry. However, the presence of pollutants in the aquatic environment has harmful effects on the environment and humans. Photocatalytic degradation can be appropriate method for water purification. Therefore, the Fe3O4/CdS-ZnS magnetic nanocomposite was synthesized and characterized by Brunauer-Emmett-Teller (BET) surface area analysis, Energy dispersive x-ray spectroscopy (EDX), X-ray diffraction (XRD), vibrating sample magnetometry (VSM), UV-Vis-diffuse reflectance spectroscopy (DRS), and field emission scanning electron microscopy (FESEM) analyses and was used to degrade pollutants such as chlorpyrifos pesticide and brilliant green dye under visible light with source 300 W. Parameters that may be effective on photocatalytic degradation include pH, photocatalyst amount, contaminant concentration, photocatalyst and contaminant contact temperature and duration, light intensity as well as distance of light source from the reaction vessel. In the present study, the parameters that have the most influence on the degradation process were experimentally optimized, including pH, photocatalyst amount, photocatalyst reuse, and initial concentration. The study of the photocatalytic degradation rate of chlorpyrifos and brilliant green in optimal conditions (pH = 7, the concentration of pollutants = 10 ppm, volume of pollutants = 5 mL, and photocatalyst amounts for CP and BG were 0.0100 and 0.0015 g respectively) was obtained by Langmuir-Hinshelwood model. According to this model, the kapp value for CP and BG were respectively 0.0315 and 0.0119 min-1 respectively. It has been concluded that the composition of CdS and ZnS caused inhibition of the recombination of photogenerated charge carriers, leading to high catalytic efficiency. Based on the results, the synthesized nanocatalyst showed that it has the ability to photocatalytic degradation of chlorpyrifos and brilliant green in aqueous solutions.