Abstract
First, the telomerization of tetrafluoroethylene (TFE) and chlorotrifluoroethylene (CTFE) with carbon tetrachloride and bromotrichloromethane were performed by using a redox initiation [1,2]: ▪Telomers la,n and lb,n can be changed into oligomers with trichloromethyl group at both ends of the chain ▪Then the bistelomerization of allyl acetate with the above telogens 2b,1 and 2b,2 : ▪We showed that copper salts allowed us to obtain 100% telechelic whereas the iron salts and RuCl2(PPh3)3 [4] led to a /34 blend and we explain such results.
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