Synthesis of carbon quantum dots/porous aromatic frameworks (CQDs/PAF-45) composites and their enhanced photocatalytic performance

Abstract

Modification and functionalization of porous aromatic framework (PAF) materials have emerged as crucial research directions in various fields. In this study, we employed a hydrothermal method to synthesize a carbon quantum dots (CQDs) solution. By loading different amounts of CQDs onto the surface of PAF-45 material through ultrasonic and hydrothermal treatments, we successfully formed CQDs/PAF-45 composite materials. The introduction of CQDs effectively transformed the hydrophobic nature of PAF-45 into a hydrophilic material, thereby overcoming the challenge of achieving efficient contact between PAF catalysts and reactants in aqueous solutions. In the photocatalytic degradation experiments of Rhodamine B (RhB), tetracycline, CQDs/PAF-45 composite materials surpassed that of the pristine PAF-45 material. Notably, the 1 wt% CQDs/PAF-45 composite material exhibited the highest photocatalytic activity, with degradation efficiencies for Rhodamine B, tetracycline, and phenol approximately 1.4 times, 1.5 times and 1.5 times higher than those of the PAF-45 material, respectively.