Synthesis of carbon dots with high photocatalytic reactivity by tailoring heteroatom doping

Abstract

The photocatalytic degradation of organic pollutant by carbon-based materials is still a challenge. Herein, xylose-derived carbon dots (X-CDs) and chitosan-derived CDs (C-CDs) were synthesized by heteroatoms-doping strategy. Although there is almost no difference in fluorescence emission behaviors, the two types of CDs demonstrated different advantages in photocatalysis and peroxymonosulfate (PMS) activation. Comparative research revealed that the X-CDs with doping of heteroatom S was superior in the separation of electron-hole pairs, resulting in a higher catalytic performance, while the S, N co-doped C-CDs can only exhibit high photocatalytic reactivity when they were coupled with PMS. The underlying reason is that the N-related functional groups with strong electron-donating property weakened the electron-trapping capacity of S-related energy level, but surface state resulting from this doping structures were conducive to promoting photo-generated electron transfer from C-CDs to PMS and played the primary role in organic oxidation. Thanks to the doping effect, both the X-CDs and C-CDs/PMS system displayed high photocatalytic performance for methylene blue removal under sunlight irradiation, showing almost 100% degradation efficiency in a 30 min period. The present study provides a valuable insight for the synthesis of CDs-based catalysts but also establishes a very promising catalytic oxidation system.