Synthesis of black TiO2 nanotubes decorated biomass-derived spongy carbon as an electrode material for producing deionized water through capacitive deionization technology

Abstract

The capacitive deionization (CDI) technique is considered a promising eco-friendly desalination method due to its high energy efficiency, ease of operation, and simplistic electrode regeneration capability. Thus, significant research is focused on developing highly efficient electrode materials with high electrochemical stability and salt electro-adsorption capacity (Sc) behavior during operation because these are the governing factors in examining the measured activity of fabricated CDI cells. In this manuscript, we report the synthesis of hydrogenated titanium nanotubes@spongy activated carbon (HTiO2 NTs@SAC) using pyrolysis and hydrothermal processes. The SAC is synthesized by the pyrolysis of spongy loofa in an inert atmosphere and further hydrothermally activating it in an aqueous potassium hydroxide solution. The hydrothermal process activates and enhances the hydrophilicity of SAC. HTiO2 is synthesized electrochemically at 20 V in 0.1 M perchloric acid. Such HTiO2 NTs@SAC configuration can provide excellent pathways to increase ion adsorption and improve the kinetics of charge transfer by enhancing the contact between the electrolyte and electrode at the interface. It is found that HTiO2 NTs@SAC has a specific capacitance (Cs) of 385.7 F g−1 compared with 332.7 F g−1 for SAC. The salt electrosorption capacity (Sc) of HTiO2 NTs@SAC electrode material is found to be 24.90 mg g−1 in 250 μS cm−1 saline solution at 1.2 V, which is much higher than the values obtained for SAC (9.8 mg g−1). HTiO2 NTs@SAC has also shown an antimicrobial effect toward gram-negative bacteria and exhibited good performance in the supercapacitor application, wherein HTiO2 NTs@SAC showed a higher Cs (505.55 F g−1) than SAC (380 F g−1) at 1 A g−1. Thus, we demonstrate that the prepared composite can be used as an energy storage material, an antibacterial material, and a CDI electrode in the CDI technology.