Abstract
AbstractSeveral β‐N‐glycosides were obtained upon a simple and efficient two‐step methodology. First, α‐1,2‐anhydrosugars were prepared diastereoselectively by the oxidation of 3,4,6‐tri‐O‐benzyl‐D‐glucal under biphasic conditions (CH2Cl2/water) using dimetyldioxirane (DMDO) generated in situ from oxone/acetone mixture and amphiphilic imidazolium ionic liquid (DodMImBF4) as phase transfer catalyst. Immediately, β‐N‐glycosides were synthesized in good yields by aminolysis of these α‐1,2‐anhydrosugars using CH3CN as solvent. The overall process allows stereoselective generation of biologically relevant carbohydrate derivatives.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
