Synthesis of a carbon nanofiber/carbon foam composite from coal liquefaction residue for the separation of oil and water

Abstract

A carbon nanofiber (CNF)/carbon foam composite was fabricated from coal liquefaction residue (CLR) through a procedure involving template synthesis of carbon foam and catalytic chemical vapor deposition (CCVD) treatment. The high solubility and high pyrolysis yield make CLR a promising carbon precursor for the synthesis of carbon materials using the template method. The carbon foam has cell size of about 500μm and a porosity as high as 95vol.%. Fe species naturally present in the CLR disperse homogeneously on the surface of the carbon foam acting as a catalyst in the CCVD process. After the CCVD treatment, the whole surface of the carbon foam is covered by entangled CNFs with external diameters of 20–100nm and lengths of several tens of micrometers. The obtained CNF/carbon foam composites are effective selective adsorbents in the separation of oil and water, through a combination of hydrophobicity and capillary action.