Abstract

• Novel 6-mercapto-2-diphenylchalcogenophosphinoylpyridines HSpyP(E)Ph 2 ; E = O, S. • Synthesis of [Re 2 (CO) 6 (SpyP(E)Ph 2 ) 2 ]; E = O, S starting from ReBr(CO) 5 . • Preparation of complexes [Re(CO) 4 SpyP(E)Ph 2 ]; E = O, S. • Synthesis of [Re 2 (CO) 6 (SpyP(E)Ph 2 ) 2 ] starting from Re(CO) 4 SpyP(E)Ph 2 ].

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