Abstract
AbstractA chemo‐ and regioselective iridium‐catalyzed dienylation of ortho‐aminostyrene derivatives with dienyl carbonates was realized. With a catalyst generated from [Ir(cod)Cl]2 (2 mol %) and a racemic phosphoramidite ligand (4 mol %), 1Z,4E,6E‐trienes were obtained in moderate to good yields with exclusive formation of a cis double bond.
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