Abstract
A new series of aryloxyporphyrins bearing benzyl and naphthyl substituents viz., ZnTBPP (1), ZnTNPP (2) and ZnONPP (3) has been synthesized and characterized by UV-vis, fluorescence and 1H NMR spectroscopic techniques and mass spectrometry. 1–3 have been utilized as donors to interact with fullerene (C[Formula: see text] acceptor to form 1:1 complex in toluene at 298 K. The subsequent investigation into quenching measurements with concomitant increase in fullerene concentration revealed effective quenching constants. The calculated association constants were in the order of 103 M[Formula: see text]. However, ZnTNPP (2) exhibited higher binding constant as compared to other analogs due to effective [Formula: see text]–[Formula: see text] interactions. ZnONPP (3) exhibited 3.4 times lower association constant than ZnTNPP (2) due to steric hindrance offered by meso-(3,5-dinapthyloxyphenyl) groups. The geometric and electronic structure of Zn(II) porphyrin-fullerene dyad was probed by DFT calculations which suggested the possibility of charge transfer from meso-aryloxyporphyrin core to fullerene C[Formula: see text].
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call