Abstract
A series of isostructural lanthanide coordination polymers (Ln-CPs) {[Ln(Cbdcp)·3H2O]·Cl·xH2O} Ln=Tb (1), Eu (2), Dy (3), Cbdcp=N-(4-carboxybenzyl)-(3,5-dicarboxyl)pyridinium, have been successfully synthesized and fully characterized. Complex 1 utilized as a representative chemosensor has the potential to serve as the first example of a luminescent Ln-CP material based on the zwitterionic type of organic ligand for selective and recyclable sensing of TNP in ethanol solution. Besides, Complex 3 has antiferromagnetic property and exhibits slow magnetic relaxation.
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