Abstract
The compound Na2Ti(CF3COO)6(CF3COOH)2 was synthesized as colorless crystals, extremely unstable in air, by the reaction of TiCl4 with trifluoroacetic acid and sodium trifluoroacetate. Crystallographic studies have shown that this sodium trifluoroacetatotitanate is the first example of a tetravalent titanium carboxylate [Ti(RCOO)6]2– containing titanium in an octahedral environment of oxygen atoms of carboxylate groups. Thermal decomposition of Na2Ti(CF3COO)6(CF3COOH)2 in an argon atmosphere results in the complex fluoride Na2TiF6.
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