Abstract
The first crystal structures of 1-sulfonyl-1,2,3-triazoles are described and studied by X-ray diffraction analyses. The referred compounds displayed C–H···O and C–H···N interactions on 1,2,3-triazole moiety, which are involved in a zigzag arrangement along the edge plane observed in these structures. The sulfonyl group has a high electrophilic character, which is increased by electronegative atoms, and is likely the cause of the sulfonyl group's significant reactivity compared to other five-membered heterocyclic rings, according to theoretical studies of molecular and electronic properties determined on 1-sulfonyl-1,2,3-triazoles.
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