Abstract
1,6-Dithiapyrene (DTPY) derivative having an imidazole moiety, DTPY-imidazole, was designed and synthesized as a new hydrogen-bonded electron-donor molecule. The electron-donating ability of the donor estimated by CV measurement was similar to that of DTPY. This molecule formed a two-dimensional network structure involving a one-dimensional H-bonded chain and π-stacking column. The TCNQ complex was characterized as a partial charge-transfer complex having a segregated structure from the IR and electronic spectra and exhibited a high electrical conductivity (5.6 × 10 −2 S cm −1 at 290 K).
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