Abstract

A new azido-bridged copper(II) complex, [Cu(dmp)(µ 1,1-N3)(µ 1,3-N3)] n (1) (dmp = 3,5-dimethylpyrazole), has been structurally and magnetically characterized. X-ray diffraction analysis indicates that the compound consists of double end-on (EO) azido-bridged dimers which are linked by single end-to-end (EE) azide bridges to form a 2-D layer-like structure. Magnetic investigation demonstrates an overall ferromagnetic interaction in 1 and both azide bridges (EE and EO) transmit ferromagnetic coupling. At low temperature (T < 2.5 K), the compound exhibits some metamagnetic behavior.

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