Abstract
The new complex, [IBzPyCH 3 ][Ni(bdt) 2 ] (1), has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction, in which [IBzPyCH 3 ]+ = 1-(4-iodobenzyl)-3-methylpyridinium and bdt 2 − = 1,2-benzene- dithiolate. The X-ray structure analysis shows that the anions are centrosymmetric, the two nonequivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H· · · S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin-canting.
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