Abstract
The synthesis, crystal structure and magnetic properties of a novel diamagnetic metal complex with thiazole‐substituted nitronyl nitroxide radicals, [Ag (NIT2‐thz)2](NO3) (NIT2‐thz=2‐(2′‐thiazole)‐4,4,5,5‐tetramethylimidazoline‐1‐oxyl‐3‐oxide), is reported. The structure of the complex consists of tetracoordinated [Ag (NIT2‐thz)2]+ cations and uncoordinated nitrate anions. The radical behaves as a bidentate chelating ligand through one nitronyl nitroxide oxygen and the thiazole nitrogen. Magnetic susceptibility data showed that there are weak intramolecular anti‐ferromagnetic interactions between the radicals in the complex.
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