Year-end Sale % OFF 
Abstract
A new nickel(II) complex, [Ni(CMP)2(dca)2] (1), and a new manganese(III) complex, [MnCl(EDS)(H2O)] (2) (CMP = 4-chloro-6-[(3-cyclohexylammoniopropylimino)methyl]phenolate, dca = dicyanamide anion, and EDS = N,N′-ethylenebis(3,5-dibromosalicylideneimine)), were prepared and characterized on the basis of elemental analyses, IR spectra, and single-crystal X-ray diffraction. X-ray determination indicates that complex 1 is a centrosymmetric mononuclear nickel(II) compound. The Ni atom, lying on an inversion center, is coordinated by O and N atoms from two Schiff base ligands, and N atoms from dca ligands, forming an octahedral coordination. Complex 2 is a mononuclear manganese(III) compound. The Mn atom is coordinated by O and N atoms of the Schiff base ligand, and water O and Cl atoms, forming an octahedral coordination. The crystals of the complexes are stabilized by hydrogen bonds. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
