Abstract
Abstract The crystal structure of a novel [Cu2(μ3-CO3)(SCN)2(py)4]n complex has been determined. It comprises of [Cu CO3 Cu]n infinite chains, running along the a-axis, and is in this aspect similar to the previously described [Cu(CO3)(4-aminopyridine)2]·H2O complex. The FTIR spectrum of [Cu2(μ3-CO3)(SCN)2(py)4]n has been recorded and analyzed. A Cu CO3 Cu intrachain coupling between Cu(II) atoms has been found to be responsible for the weak ferromagnetic properties of [Cu2(μ3-CO3)(SCN)2(py)4]n.
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