Abstract
Two novel Ln–Ag coordination compounds with the formula [LnAg 2(IN) 4(OAC) · 5H 2O] · 2H 2O (Ln = Gd 1, Eu 2; HIN = isonicotinic acid; HOAC = acetic acid) have been synthesized under hydrothermal condition and characterized by single-crystal X-ray diffraction, thermal analysis, IR absorption spectroscopy, ultraviolet excitation and emission spectrum. The two compounds show isostructural architectures and exhibit an unusual 1-D structure, which is formed by the linkages of Ag–Ag.
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