Abstract
The synthesis and characterization of bischelated silver(I) complexes of L(1) (L = 2-arylpyridinecar☐aldimine), [AgL 2]ClO 4 is reported. Solutions of the complexes are stable in methanol and chloroform, but unstable in acetonitrile. The chemical reactions of the silver complexes with chlorides of iron(III), cobalt(II) and nickel(II) have been examined. In all cases metal-exchange reactions take place to yield ML 3 2+ [M = iron(II), cobalt(II) and nickel(II)]. These compounds have been characterized by comparison of their spectral data with those of authentic samples. The redox properties of the compounds are also briefly noted.
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