Abstract
The interaction between methylene blue–Dy(III) complex and herring sperm DNA was investigated in physiological buffer (pH 7.40). The binding ratios and the apparent molar absorptivity of ϵ MB-Dy-DNA were determined by the molar ratio method. The thermodynamic parameters were calculated by a double-reciprocal equation at different temperatures, and showed that the interaction of methylene blue–Dy(III) complex with DNA was driven mainly by Δr S Θ m. By combination analysis of the Scatchard method, viscosity measurements, ferrocyanide quenching experiments, and circular dichroism spectroscopy, the methylene blue–Dy(III) complex can bind to DNA, and the major binding mode is electrostatic and partial intercalation binding.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
