Abstract
A pair of new structurally similar mononuclear Schiff base copper(II) and zinc(II) complexes, [CuL2] · 2ClO4 (1) and [ZnL2(ClO4)2] (2) (L=2‐bromo‐4‐chloro‐6‐[(2‐isopropylaminoethylimino)methyl]phenol), have been synthesized and characterized by elemental analysis, IR and single crystal X‐ray diffraction. Each Cu atom in (1) is four‐coordinated by two phenolate O and two imine N atoms from two Schiff base ligands, forming a square‐planar coordination. Each Zn atom in (2) is six‐coordinated by two phenolate O and two imine N atoms from two Schiff base ligands, and by two O atoms from two perchlorate anions, forming an octahedral coordination. The different metal perchlorate salts used in the preparation of the complexes with the Schiff base ligand can result in the similar structures of the final products.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
