Year-end Sale % OFF 
Abstract
A new crystal of tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-nickelate acetone solvate (BPNI) has been prepared at room temperature and characterized by elemental analysis, UV–Vis–NIR absorption spectrum and X-ray single crystal determination. The complex crystallized in monoclinic space group P2/c with unit cell dimensions a = 24.5350 (6) A, b = 7.3097 (2) A, c = 23.1141 (6) A, β = 115.585 (2)°, V = 3738.89 (17) A3, Z = 4, D x .= 1.5081 (1) g cm−3. The X-ray structure determination revealed that the crystal is centro-symmetrical and there are two halves of independent cations in the molecule. A new crystal of tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-nickelate(II) acetone solvate (BPNI) with monoclinic space group P2/c (unit cell dimensions a = 24.5350(6) A, b = 7.3097(2) A, c = 23.1141(6) A, β = 115.585(2)°, V = 3738.89(17) A3, Z = 4, D x = 1.5081(1) g cm−3) has been prepared and characterized by elemental analysis, UV–Vis–NIR absorption spectrum and X-ray single crystal determination.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
