Abstract
The reaction of 1-trifluoromethyl-3-(1′-pyreno)-1,3-propanedione with lanthanum(III) trichloride in the presence of pyridine leads to halide ligand exchange, yielding a novel pyridinium tetrakis{1-trifluoromethyl-3-(1′-pyreno)-1,3-propanedionato}lanthanate(III) complex with four polycyclic aromatic hydrocarbon moieties. This reaction easily proceeds under mild conditions (25°C, 24 h) producing the complex in a 90% isolated yield. The complex was characterized by infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and positive fast atom bombardment mass spectrometry, and its precise structure was determined by single crystal X-ray diffraction. Ultraviolet-visible spectroscopy, fluorescence spectroscopy, and X-ray analysis demonstrated that the four pyrene moieties were independently oriented.
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