Abstract
One new title compound [Co(BIBP)(mpa)] n ( 1 ) (BIBP = 4,4′-biimidazole biphenyl, mpa = m-phthalic acid) has been synthesized under solvothermal condition. The title compound was characterized by IR spectra, thermal analysis, single crystal and powder X-ray diffraction. The results prove that the alliance of BIBP and aromatic carboxylic acids is good for diversity of the getatable structure. Magnetic susceptibility measurements indicate that compound 1 exhibits antiferromagnetic coupling between adjacent Co(II) ions. In addition, the photochemical properties have been investigated. One new title compound [Co(BIBP)(mpa)] n has been synthesized under solvothermal condition. Magnetic susceptibility measurements indicate that compound exhibits antiferromagnetic coupling between adjacent Co(II) ions. • A new Co coordination polymer with mixed-ligands has been synthesized. • The 2D framework was proven by single-crystal X-ray diffraction. • Title compound exhibits antiferromagnetic coupling between adjacent Co(II) ions.
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