Abstract
Colourless block-shaped crystals of Dichloro{2-methoxy-6-[(3-cyclohexylaminopropy-limino)methyl]phenolato}zinc(II) methanol, [Zn(C17H26N2O2)Cl2].CH3OH, have been obtained and characterized by elemental analysis, IR and X-ray single crystal determination. The complex crystallizes in the monoclinic space group P21/n with unit cell dimensions a=12.980(3) A, b=13.139(3) A, c=13.277(3) A, β=107.00(3)°, V=2165.4(8) A3, Z=4, R 1=0.0631 and wR2=0.1110. X-ray structure determination revealed that the complex consists of a [Zn(C17H26N2O)Cl2] moiety and a lattice MeOH molecule. In the crystal structure, molecules are linked through intermolecular N–H $$\cdots$$ O, C–H $$\cdots$$ Cl and O–H $$\cdots$$ Cl hydrogen bonds, forming chains. It is the first complex derived from the Schiff base ligand 2-methoxy-6-[(3-cyclohexylaminopropylimino)methyl]phenol.
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