Abstract
Reactions of 2-(arylazo)aniline, L-NH2 [L-NH2 = p-RC6H4N=NC6H4NH2; where R=H for L1-NH2, CH3 for L2-NH2 and Cl for L3-NH2] with [Os(H)Br(CO)(PPh3)3] gave the complexes [OsBr(L-NH)(CO)(PPh3)2] for which cyclic volatammograms exhibited one quasi-reversible oxidative response within the range 0.54–0.6 V vs SCE. The X-ray crystal structure of [OsBr(L1-NH)(CO)(PPh3)2] has been determined and its electronic structure was evaluated on the basis of single point DFT calculations using its crystallographic coordinates.
Full Text
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call