Synthesis and study of thermal, mechanical and biodegradation properties of chitosan-g-PMMA with chicken egg shell (nano-CaO) as a novel bio-filler

Abstract

The important objective of this study is to evaluate the effect of chicken eggshell (nano-Cao) as a functionalized bio-filler on the mechanical strength and thermal stability of acrylic based bionanocomposite of chitosan grafted with poly(methyl methacrylate)(PMMA). The chitosan grafted PMMA adsorbed with functionalized biofiller was prepared via emulsion polymerisation technique and physicochemically characterized as bone graft substitute. The so prepared grafted bioactive bone cement (BBC) bionanocomposite (BNC), chitosan-g-PMMA/nano-CaO was characterized by FTIR, XRD, FESEM and TGA. The water uptake, retention ability, their biodegradability and the nanosize particle arrangement in the polymeric BBC-BNCs were undertaken. These preliminary investigations of the BNCs will open the door for their use in bioadhesive bone cement implants in future.