Synthesis and structure of two lanthanide complexes with isonicotinic acid N-oxide (HL): [Ln(L) 2(H 2O) 4] n·(NO 3) n· n(H 2O) (Ln = Sm or Tb)

Abstract

Two new lanthanide complexes of isonicotinic acid N-oxide (HL), namely [Ln(L) 2(H 2O) 4] n ·(NO 3) n · n(H 2O) for Ln = Sm or Tb, have been synthesized and characterized by spectroscopic and crystallographic methods. IR spectra suggest that isonicotinic acid N-oxide acts as a O,O′-bidentate ligand, the N-oxide group as well as the nitrate group are not involved in coordination. Single crystal analyses have shown that both complexes are isomorphous, where the Ln(III) centers are eight coordinated by four O atoms of four water ligands and other four O atoms of two isonicotinic acid N-oxide ligands. The carboxylate groups are only involved in the bidentate syn–syn bridging mode into infinite chains. Hydrogen bonds between aqua ligands, lattice molecules, nitrate and N-oxide groups are formed giving a three-dimensional network.