Abstract
A 1,2sigma5-selenaphosphirane bearing the Martin ligand was synthesized. Its structure in both the solid and the solution state was established by X-ray crystallographic analysis and NMR measurements, respectively. The selenaphosphirane has a polar P-Se bond, and the selenium atom is negatively charged. In the solution state, the degree of polarization of the P-Se bond depends on the acceptor number of the solvents.
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