Abstract

Oxidation of the mononuclear semiquinonediimine complex [(NPh)(NH)C6H4]2Pd with silver trifluoromethanesulfonate afforded the diamagnetic dinuclear dicationic palladium complex {[(NPh)(NH)C6H4]2Pd}2(O3SCF3)2 with a Pd...Pd distance of 3.267(1) A. The complex was structurally characterized, and its spectroscopic and electrochemical properties were studied.

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