Abstract
New symmetrical metal complexes of the rare-earth element phthalocyanines were synthesized by the reaction of 4,5-bis(cyclohexylmethoxy)phthalonitrile, obtained for the first time, with the rare-earth element salts, as well as starting from the corresponding free phthalocyanine. A correlation between method of the synthesis and the reaction product compositions was studied. Structures of the complexes obtained were confirmed by mass spectrometry, X-ray crystallography, and electronic absorption spectroscopy. All the metal complexes are well soluble in organic solvents.
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