Abstract

Under hydrothermal condition, a 1D chain metal phosphate-phosphite oxalate V2O2(HPO4)(HPO3)(C2O4)2·(C4N2H12)2·2H2O (1) was synthesized. The resultant sample exhibited excellent water and acid-base stability. In addition, due to the presence of crystal water molecules, compound 1 has good proton conductivity. Under 98% RH and 75 °C, the proton conductivity of the compound can reach 4.35 × 10−4 S·cm−1.

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