Abstract
Two new dioxomolybdenum(VI) complexes, [MoO2L1(CH3 OH)] (1) and [MoO2L2(CH3OH)] (2), where L1 and L2 are the dianionic form of isonicotinic acid (1-methyl-3-oxobutylidene) hydrazide and nicotinic acid (1-methyl-3-oxobutylidene)hydra- zide, respectively, were prepared and structurally characterized by physicochemical and spectroscopic methods and single crystal X-ray determination. The complexes are mononuclear molybdenum compounds. The Mo atom in each complex is in octahedral coordination. The catalytic property of the complexes indicates that they are effective catalyst for sulfoxidation.
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