Abstract
A new nickel(II) complex, [NiL 2]Cl 2 (L= N, N-bis(benzimidazol-2-yl-methyl)amine), was synthesized and its crystal structure was determined. According to X-ray crystallographic studies, each nickel(II) ion was six-coordinated with six nitrogen atoms of two L ligands. The complex crystallizes in triclinic system, space group P 1 ̄ , a=9.764(3) A ̊ , b=11.032(3) A ̊ , c=16.402(5) A ̊ , α=80.529(6)°, β=79.180(7)°, γ=74.232(6)°, and Z=2. The title complex forms two-dimensional hydrogen bond network structures between the chlorine atoms and the nitrogens of L. The IR and UV spectroscopy were measured. The absorption bands of d–d electron transition are assigned, the values of Dq and B were calculated according to the electronic spectrum of the complex.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
