Abstract
A new nickel(II) complex, [NiL 2]Cl 2 (L= N, N-bis(benzimidazol-2-yl-methyl)amine), was synthesized and its crystal structure was determined. According to X-ray crystallographic studies, each nickel(II) ion was six-coordinated with six nitrogen atoms of two L ligands. The complex crystallizes in triclinic system, space group P 1 ̄ , a=9.764(3) A ̊ , b=11.032(3) A ̊ , c=16.402(5) A ̊ , α=80.529(6)°, β=79.180(7)°, γ=74.232(6)°, and Z=2. The title complex forms two-dimensional hydrogen bond network structures between the chlorine atoms and the nitrogens of L. The IR and UV spectroscopy were measured. The absorption bands of d–d electron transition are assigned, the values of Dq and B were calculated according to the electronic spectrum of the complex.
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