Abstract
Black single crystals of Cs2U2(P2Se9)(Se2)2 were synthesized at 1023 K by a solid‐state reaction. Its structure was determined by single‐crystal X‐ray diffraction methods. The compound is isostructural with Rb2U2(P2Se9)(Se2)2 and Cs2Th2(P2Se9)(Se2)2 compounds, and crystallizes in the orthorhombic space group Pbca. Cs2U2(P2Se9)(Se2)2 displays a three‐dimensional structure comprising USe9 polyhedra connected via the Se22– and P2Se9 species with channels filled by Cs atoms. From electronic structure calculations the compound is found to be a metal with a ferromagnetic arrangement of the magnetic moments.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Zeitschrift für anorganische und allgemeine Chemie
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
