Abstract
A novel inorganic–organic hybrid polyoxometalate, [1,1′-dibutyl-4,4′-bipyridinium,][α-Mo8O26]0.5 (1), has been synthesized by the cation-templated self-assembly with octamolybdate anions under hydrothermal reaction conditions. The structure has been determined by single-crystal X-ray diffraction analysis and further characterized by PXRD, IR spectra, and elemental analysis. The crystal data analysis revealed that the compound was composed of one discrete [1,1′-dibutyl-4′-bipyridinium]2+ cation and 0.5 polyacid anions [Mo8O26]4– interacted by electrostatic interactions. In the compound the anion fraction take on a [α-Mo8O26]4– cluster.
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